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1Bradley Cooper

Before Cooper became a mega-watt Hollywood director, one of his first notable roles was playing Jason Whitaker in the season six SVU episode, "Night." Whitaker was a seemingly charming lawyer dealing with a client accused of raping illegal immigrants. In the end, it's revealed that the client's wealthy family was paying Whittaker off to cover for him all along.
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2Cynthia Nixon

A few years after Sex and The City wrapped, Nixon took on an entirely different role in the season nine opening episode, "Alternate," which was full of the show's signature plot twists and turns. Nixon played Janis Donovan, a mother falsely accused of abusing her daughter, who was also faking Dissociative Identity Disorder to cover up a murder. Nixon gave such an impressive performance that she won an Emmy for the role.
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3Robin Williams
In SVU's 200th episode during season nine, Williams played Merritt Rook, an anti-authoritarian activist who abducts Olivia Benson to challenge authority. Rook's crimes were actually based on a true story.
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4Alec Baldwin
Baldwin appeared as Jimmy MacArthur for Mariska Hargitay's directorial debut in season 15. MacArthur, a controversial newspaper columnist with powerful influence over the New York City authorities, makes things especially difficult for the Special Victims Unit...before having a change of heart.
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5Milo Ventimiglia
Prior to his This Is Us stardom, Ventimiglia took a break from his bad-boy bit on Gilmore Girls to tackle the part of Lee Healy in season five's "Escape." At first, it seemed that Healy had been sexually abused by his stepfather as a kid, but in typical SVU fashion, things were not as they appeared: he was actually involved in a secret, incestuous relationship with his cousin.
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6Amanda Seyfried
Seyfried made an appearance in the season six episode "Outcry," where she played rape victim, Tandi McCain. In a truly twisting plot line—even by SVU standards—McCain changed her story on perpetrator several times before the truth was revealed.
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7Carol Burnett
Even some of Hollywood's greatest legends have added SVU cameos to their resumes. In season 10, Burnett played Birdie Sulloway; a serial killer who married and murdered several men who she deemed unworthy to remain in this world.
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8John Stamos
In the cheekily titled season 12 episode, "Bang," Stamos played lawyer Ken Turner, a master manipulator who had fathered at least 20 children, and made reproductive rights the hot topic of the moment down at the station.
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9Kathy Griffin
In season 11, Griffin took a little break from comedy to play Babs Duffy, the leader of lesbian rights group, LesBeStrong. Duffy accuses the SVU team of neglecting crimes against the lesbian community due to homophobia, before her own sexuality is outed.
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10Zoe Saldana
Saldana played Gabrielle Vega, the daughter of a convicted murderer, in the season five episode "Criminal." Vega entered the scene when the SVU team discovered that her father had been framed for murder at 19-years-old, before he even knew Vega existed. When her father went back to using drugs, Vega filed a lawsuit against the NYPD, seeking reparation.
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11Hilary Duff
During the season 10 episode "Selfish," Duff portrays Ashlee Walker, a young and seemingly irresponsible mother—a far cry from Lizzie McGuire. When Walker's daughter dies of measles after being exposed to an unvaccinated child, the sick child's family becomes a target for revenge.
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12Jennifer Love Hewitt
Some SVU episodes are a little more disturbing than others, and season 12's "Behave" certainly leaves you feeling uneasy. Hewitt plays Vicki Sayers, a woman who told detectives she had been raped for the fourth time in 15 years by the same man. Despite widespread doubt, Olivia Benson helps her catch and convict her attacker.
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13Angela Lansbury
Lansbury appeared in the season six episode, "Night" alongside Bradley Cooper, taking on the role of Eleanor Duvall. The wealthy and politically-driven mother of a suspected serial rapist, she's found to be paying off Cooper's character in exchange for his silence.
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14Eric McCormack
In season 11, McCormack appeared in the episode "Sugar," where he played Vance Shepard, the CEO of a dating website. Shepard is accused of murdering a young woman, but in a typical SVU twist, we learn that a family member is the one who committed the crime—will they manage to off him before serving time themselves?
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15Henry Winkler
In the season three episode aptly titled "Greed," Winkler played con-man Edward Crandall, who married a woman for her money, then attempted to pass off her death as a rape/burglary.
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16James Van Der Beek
Van Der Beek takes a 180-degree turn from sweet Dawson Leery to creepy Sean Albert in season 13's episode, "Father Dearest." He's unsettlingly convincing as Albert, a man who takes advantage of teen girls searching for their biological fathers online. After seducing the daughter of his ex-girlfriend, he finds himself in hot water.
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17T.R. Knight
Knight starred in the season 13 episode "Double Strands," where he split his time between portraying Gabriel Thomas and Brian Smith—identical twins accused of rape. Thomas adamantly denies the accusation, but it takes some time to pinpoint his more sinister brother.
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18John Ritter
In the season three episode "Monogamy," Ritter played Dr. Richard Manning. His character was a doctor accused of a grim crime: murdering his wife, and then removing her unborn child from the womb.
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19Sarah Hyland
Hyland is one of a handful of stars who appeared on Law & Order not once, but twice. She first starred in season three, playing a child victim in the episode, "Repression," then returned in season 10 to play a less innocent role. In "Hothouse," Hyland portrayed Jennifer Banks, a student who suffers from a psychotic breakdown and admits to murdering her roommate.
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20Brad Garrett
After his Everybody Loves Raymond years, Garrett took on a cop role once more during season 17 of SVU. This portrayal wasn't a laughing matter, however—over two episodes he played Gary Munson, a crooked corrections officer who had been abusing female inmates. When Munson is eventually arrested, he doesn't go quietly, and ends up being partially responsible for the death of Sgt. Mike Dodds.
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